Issue 12, 2010

Advanced microwave-assisted production of hybrid electrodes for energy applications

Abstract

Carbon nanotubes are one of the most prominent materials in research for creating electrodes for portable electronics. When coupled with metallic nanoparticles the performance of carbon nanotube electrodes can be dramatically improved. Microwave reduction is an extremely rapid method for producing carbon nanotube-metallic nanoparticle composites, however, this technique has so far been limited to carbon nanotube soot. An understanding of the microwave process and the interactions of metallic nanoparticles with carbon nanotubes have allowed us to extend this promising functionalisation route to pre-formed CNT electrode architectures. Nanoparticle reduction onto pre-formed architectures reduces metallic nanoparticle waste as particles are not formed where there is insufficient porosity for electrochemical processes. A two-fold increase in capacitive response, stable over 500 cycles, was observed for these composites, with a maximum capacitance of 300 F gāˆ’1 observed for a carbon Nanoweb electrode.

Graphical abstract: Advanced microwave-assisted production of hybrid electrodes for energy applications

Article information

Article type
Paper
Submitted
11 Aug 2010
Accepted
22 Sep 2010
First published
14 Oct 2010

Energy Environ. Sci., 2010,3, 1979-1984

Advanced microwave-assisted production of hybrid electrodes for energy applications

P. C. Sherrell, J. Chen, J. M. Razal, I. P. Nevirkovets, C. Crean, G. G. Wallace and A. I. Minett, Energy Environ. Sci., 2010, 3, 1979 DOI: 10.1039/C0EE00352B

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