Issue 25, 2011
From the journal:

Chemical Communications

Synthesis and structure of [Na4(DMSO)15][(I3)3(I)]. Self-assembly of hexacoordinated sodium†‡

Álvaro Duarte-Ruiz,*a   Nelson Nuñez-Dallos,a   Luis Garzón-Tovar,a   Klaus Wurst,b   Eliseo Avella-Morenoa  and  Fernando Gómez-Baqueroc  

* Corresponding authors

a Departamento de Química, Universidad Nacional de Colombia, Ciudad Universitaria, Bogotá Kr 30 No 45-03, Colombia
E-mail: aduarter@unal.edu.co
Tel: +57-1-3165000. Ext. 14444

b Institute of General, Inorganic and Theoretical Chemistry, University of Innsbruck, 6020, Innrain 52a, Innsbruck, Austria

c College of Nanoscale Science and Engineering, University at Albany SUNY, USA

Abstract

A new complex with the molecular formula [Na4(DMSO)15][(I3)3(I)] represents the first example of Na+ coordinated solely by DMSO. The triiodide (I3−) and iodide (I−) anions form an infinite linear chain running throughout the crystal.

Graphical abstract: Synthesis and structure of [Na4(DMSO)15][(I3)3(I)]. Self-assembly of hexacoordinated sodium

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Article information

DOI
https://doi.org/10.1039/C1CC11898F
Article type
Communication
Submitted
03 Apr 2011
Accepted
05 May 2011
First published
26 May 2011

Chem. Commun., 2011,47, 7110-7112

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Synthesis and structure of [Na4(DMSO)15][(I3)3(I)]. Self-assembly of hexacoordinated sodium

Á. Duarte-Ruiz, N. Nuñez-Dallos, L. Garzón-Tovar, K. Wurst, E. Avella-Moreno and F. Gómez-Baquero, Chem. Commun., 2011, 47, 7110 DOI: 10.1039/C1CC11898F

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