Issue 52, 2012
From the journal:

Chemical Communications

Guanidine catalyzed aerobic reduction: a selective aerobic hydrogenation of olefins using aqueous hydrazine†

Manjunath Lamani,a   Ravikumara Siddappa Guralamataa  and  Kandikere Ramaiah Prabhu*a  

* Corresponding authors

a Department of Organic chemistry, Indian Institute of Science, Bangalore 560 012, Karnataka, India
E-mail: prabhu@orgchem.iisc.ernet.in
Fax: +91-80-23600529

Abstract

An efficient aerobic reduction of olefins, internal as well as terminal, is developed using guanidine as an organocatalyst. A remarkable chemoselectivity in reduction has been demonstrated in the presence of a variety of functional groups and protective groups and a selective reduction of a terminal olefin in the presence of an internal olefin is revealed.

Graphical abstract: Guanidine catalyzed aerobic reduction: a selective aerobic hydrogenation of olefins using aqueous hydrazine

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Article information

DOI
https://doi.org/10.1039/C2CC32611F
Article type
Communication
Submitted
12 Apr 2012
Accepted
08 May 2012
First published
09 May 2012

Chem. Commun., 2012,48, 6583-6585

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Guanidine catalyzed aerobic reduction: a selective aerobic hydrogenation of olefins using aqueous hydrazine

M. Lamani, R. S. Guralamata and K. R. Prabhu, Chem. Commun., 2012, 48, 6583 DOI: 10.1039/C2CC32611F

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