Reaction of (+)-car-2-ene (1) with (MeCN)2PdCl2 Produces a mixture of isomeric π-allypalladium complexes (2) and (3) where (2) was shown to arise from inversion of configuration at the carbon attacked by the metal.
M. U. Ahmad, Jan-E. Bäckvall, R. E. Nordberg, T. Norin and S. Strömberg, J. Chem. Soc., Chem. Commun., 1982, 321 DOI: 10.1039/C39820000321
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