The nature and the isomeric distribution of the neutral products obtained from the gas-phase attack of CH5+, C2H5+, and CH3FCH3+ ions on cyclic CnH2nO(n= 2,3, and 4) ethers provide the first experimental evidence in favour of 1-methyl-1-oxoniacyclopropane and 1-methyl-1-oxoniacyclobutane as stable intermediates on the corresponding potential energy surface.
G. Angelini and M. Speranza, J. Chem. Soc., Chem. Commun., 1983, 1217 DOI: 10.1039/C39830001217
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