Issue 14, 1984
From the journal:

Journal of the Chemical Society, Chemical Communications

Nitrous oxide as a nucleophile in the formation of a new reactive intermediate from benzyl cations in the solvolysis of benzyl azoxytosylate

H. Maskill  and  William P. Jencks  

Abstract

Rate and product analytical results of solvolysis of benzyl azoxytosylate in 1 : 1 (v/v) trifluoroethanol: water require two product-forming routes: one involves a long-lived intermediate (formed from benzyl cations and nitrous oxide) which is trappable by dilute nucleophiles and bases; the other involves either a very short-lived intermediate (the benzyl cation) which is not capable of being intercepted by solutes, or no intermediate at all.

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Article information

DOI
https://doi.org/10.1039/C39840000944
Article type
Paper

J. Chem. Soc., Chem. Commun., 1984, 944-946

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Nitrous oxide as a nucleophile in the formation of a new reactive intermediate from benzyl cations in the solvolysis of benzyl azoxytosylate

H. Maskill and W. P. Jencks, J. Chem. Soc., Chem. Commun., 1984, 944 DOI: 10.1039/C39840000944

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