Issue 15, 1984

Extraction of highly hydrophilic anions in low polarity media under phase-transfer catalysis conditions: dramatic enhancement of the OH reactivity by reduction of its specific hydration

Abstract

In the chlorobenzene–aqueous NaOH two-phase system, an increase in NaOH concentration from 5 to 20 M reduces the OH hydration sphere of the tetrahexylammonium hydroxid (1a) dissovled in chlorobenzene form 11 to 3.5 molecules of water, thus producing a dramatic incras (up to 104 times) in OH reactivity.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1984, 1041-1042

Extraction of highly hydrophilic anions in low polarity media under phase-transfer catalysis conditions: dramatic enhancement of the OH reactivity by reduction of its specific hydration

D. Landini and A. Maia, J. Chem. Soc., Chem. Commun., 1984, 1041 DOI: 10.1039/C39840001041

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