A new methodology for the ortho-hydroxylation of aromatic aldehydes via ortho-lithiated aromatic amino alkoxides provides easy access to 2-hydroxypyrene-1-carbaldehyde, a valuable precursor for biologically important pyrenofurans and pyrenocoumarins.
J. Einhorn, J. Luche and P. Demerseman, J. Chem. Soc., Chem. Commun., 1988, 1350 DOI: 10.1039/C39880001350
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