Issue 8, 1990

Reaction of carbonyl oxides and thioketones. [3 + 2] Cycloaddition vs. oxygen atom transfer

Abstract

The ozonolysis of vinyl ethers (1a,b) in the presence of thioadamantan-2-one (4a) gave in each case the corresponding thin-ozonide (5a,b) in around 70% yield, whilst ozonolysis of a mixture of vinyl ethers (1ac) and thiobenzophenone derivatives (4bd) gave the corresponding thione-S-oxides (8bd) in 15–30% yields, together with the benzophenones (6bd).

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1990, 625-627

Reaction of carbonyl oxides and thioketones. [3 + 2] Cycloaddition vs. oxygen atom transfer

T. Tabuchi, M. Nojima and S. Kusabayashi, J. Chem. Soc., Chem. Commun., 1990, 625 DOI: 10.1039/C39900000625

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements