Oxidation of alkanes such as cyclohexane, cyclooctane, adamantane and octane with 70% aqueous tert-butyl hydroperoxide in benzene in the presence of Mn2+-exchanged clay catalyst and molecular sieves 4 Å produces mainly the corresponding ketones with high turnover numbers.
J. Tateiwa, H. Horiuchi and S. Uemura, J. Chem. Soc., Chem. Commun., 1994, 2567 DOI: 10.1039/C39940002567
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