Decomposition of [{(C5Me5)Rh(µ-CH2)}2(Ph)(CO)]+(homogeneously, under CO) in solution gives PhCH![[double bond, length half m-dash]](https://www.rsc.org/images/entities/char_e006.gif)
CH2, PhMe and C6H6, while phenyl (from Phi) reacts with surface methylene (from CO + H2) heterogeneously over rhodium metal to give PhEt, PhMe and C6H6; it is proposed that the two reactions are also related mechanistically.
Z. Wang, H. C. Long, M. L. Turner and P. M. Maitlis, J. Chem. Soc., Chem. Commun., 1995, 1089 DOI: 10.1039/C39950001089
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