Issue 15, 2013

On-chip capacitively coupled contactless conductivity detection using “injected” metal electrodes

Abstract

We demonstrate the use of injected gallium electrodes for capacitively coupled contactless conductivity detection (C4D) within a microchip electrophoresis device. Evaluation of the electrodes for quantitative detection of electrophoretically separated lithium, sodium and potassium ions showed the system offers competitive detection limits of 6.1 × 10−6 M, 6.7 × 10−6 M and 8.5 × 10−6 M, respectively. The fabrication process is fast, highly reproducible, and eliminates difficulties with electrode alignment. Using this approach C4D can be readily achieved in any microchip by simply adding extra ‘electrode’ channels to the microchip design.

Graphical abstract: On-chip capacitively coupled contactless conductivity detection using “injected” metal electrodes

Supplementary files

Article information

Article type
Communication
Submitted
29 Apr 2013
Accepted
03 Jun 2013
First published
04 Jun 2013

Analyst, 2013,138, 4275-4279

On-chip capacitively coupled contactless conductivity detection using “injected” metal electrodes

L. D. Thredgold, D. A. Khodakov, A. V. Ellis and C. E. Lenehan, Analyst, 2013, 138, 4275 DOI: 10.1039/C3AN00870C

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