Issue 12, 2014
From the journal:

Chemical Communications

Hysteretic spin crossover in iron(ii) complexes of a new pyridine–triazole–pyrazine ligand is tuned by choice of NCE co-ligand†

Ross W. Hogue,a   Reece G. Miller,a   Nicholas G. White,a   Humphrey L. C. Feltham,a   Guy N. L. Jamesona  and  Sally Brooker*a  

* Corresponding authors

a Department of Chemistry and MacDiarmid Institute for Advanced Materials and Nanotechnology, University of Otago, PO Box 56, Dunedin, New Zealand
E-mail: sbrooker@chemistry.otago.ac.nz
Fax: +64 3 4797906
Tel: +64 3 4797919

Abstract

A family of three new mononuclear complexes of the general form [Fe(Lpz)2(NCE)2] has been prepared (Lpz = 4-p-tolyl-3-(2-pyrazinyl)-5-(2-pyridyl)-1,2,4-triazole; E = S, Se, BH3). All three exhibit spin crossover, in two cases with hysteresis, with T1/2 being predictably tuned by varying the coordinated anion.

Graphical abstract: Hysteretic spin crossover in iron(ii) complexes of a new pyridine–triazole–pyrazine ligand is tuned by choice of NCE co-ligand

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Article information

DOI
https://doi.org/10.1039/C3CC43922D
Article type
Communication
Submitted
25 May 2013
Accepted
10 Dec 2013
First published
11 Dec 2013

Chem. Commun., 2014,50, 1435-1437

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Hysteretic spin crossover in iron(II) complexes of a new pyridine–triazole–pyrazine ligand is tuned by choice of NCE co-ligand

R. W. Hogue, R. G. Miller, N. G. White, H. L. C. Feltham, G. N. L. Jameson and S. Brooker, Chem. Commun., 2014, 50, 1435 DOI: 10.1039/C3CC43922D

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