Issue 44, 2013

Nickel catalyzed one pot synthesis of biaryls under air at room temperature

Abstract

A practical, room temperature catalytic system has been developed for the synthesis of biaryls in one step from the homocoupling of in situ generated Grignard reagents using a nickel(II) complex. The use of atmospheric oxygen as the oxidant makes the system environmentally friendly. The reaction system is compatible with diverse functionality to afford biaryls in appreciable yields.

Graphical abstract: Nickel catalyzed one pot synthesis of biaryls under air at room temperature

Supplementary files

Article information

Article type
Paper
Submitted
02 Jul 2013
Accepted
06 Sep 2013
First published
06 Sep 2013

RSC Adv., 2013,3, 22191-22198

Nickel catalyzed one pot synthesis of biaryls under air at room temperature

A. P. I. Bhat, F. Inam and B. R. Bhat, RSC Adv., 2013, 3, 22191 DOI: 10.1039/C3RA43363C

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