Issue 2, 2015

The stabilization of gallane and indane by a ring expanded carbene

Abstract

7Dipp Complexes of the group 13 binary hydrides GaH3 and InH3 have been prepared. Both adducts possess excellent thermal stability in the solid state but decompose readily in solution at ambient temperature. The presence of short M–H⋯H–CAlkyl distances in the structures of both [MH3(7Dipp)] complexes is discussed.

Graphical abstract: The stabilization of gallane and indane by a ring expanded carbene

Supplementary files

Article information

Article type
Communication
Submitted
06 Oct 2014
Accepted
18 Nov 2014
First published
18 Nov 2014

Dalton Trans., 2015,44, 498-500

Author version available

The stabilization of gallane and indane by a ring expanded carbene

A. R. Leverett, A. I. McKay and M. L. Cole, Dalton Trans., 2015, 44, 498 DOI: 10.1039/C4DT03489A

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