Issue 47, 2014

Long-range correlation effects in directional living polymers

Abstract

The statistics of (equilibrium) living polymers including both linear chains and rings are considered theoretically. Particular attention is addressed to directional polymers characterized by an arrow along the backbone defined by its chemical structure. Thermodynamic and correlation properties of living polymers are studied both in the mean-field and in the critical scaling regimes. It is shown that living polymers with no rings, classical living polymers with rings, and directional living polymers with rings form three distinct classes characterized by different critical exponents and qualitatively different long-range correlation functions.

Graphical abstract: Long-range correlation effects in directional living polymers

Article information

Article type
Paper
Submitted
09 May 2014
Accepted
15 Sep 2014
First published
15 Sep 2014

Soft Matter, 2014,10, 9534-9561

Author version available

Long-range correlation effects in directional living polymers

A. N. Semenov, Soft Matter, 2014, 10, 9534 DOI: 10.1039/C4SM01017E

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