Issue 8, 2015

Highly efficient and stable peracid for rapid and selective oxidation of aliphatic amines to oximes

Abstract

A novel, transition-metal free, rapid approach for selective oxidation of aliphatic and benzylic amines to oximes is described. The dodecanebis(peroxoic acid)–DMF combination efficiently oxidizes various aliphatic amines at 50 °C temperature to give 100% conversion in 20 min with high oxime selectivity. The peroxy acid used here shows exceptional stability at room temperature and is non-shock sensitive in nature, which was confirmed by differential scanning colorimetric (DSC) analysis.

Graphical abstract: Highly efficient and stable peracid for rapid and selective oxidation of aliphatic amines to oximes

Supplementary files

Article information

Article type
Paper
Submitted
31 Mar 2015
Accepted
01 Jul 2015
First published
01 Jul 2015

New J. Chem., 2015,39, 6677-6682

Highly efficient and stable peracid for rapid and selective oxidation of aliphatic amines to oximes

V. V. Patil, E. M. Gayakwad and G. S. Shankarling, New J. Chem., 2015, 39, 6677 DOI: 10.1039/C5NJ00801H

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