Issue 13, 2018
From the journal:

Chemical Communications

Light-induced cross-linking and post-cross-linking modification of polyglycidol†

F. Marquardt,a   M. Bruns,b   H. Keul, ORCID logo *a   Y. Yagci ORCID logo c  and  M. Möller*a  

* Corresponding authors

a Institute of Technical and Macromolecular Chemistry, RWTH Aachen University and DWI-Leibniz-Institute for Interactive Materials, Forckenbeckstr. 50, D-52056 Aachen, Germany
E-mail: Keul@dwi.rwth-aachen.de, Moeller@dwi.rwth-aachen.de

b Karlsruhe Institute of Technology (KIT), Institute for Applied Materials (IAM-WPT) and Karlsruhe Nano Micro Facility (KNMF), Hermann-von-Helmholtz-Platz 1, Eggenstein-Leopoldshafen, Germany

c Istanbul Technical University, Department of Chemistry, Maslak, Istanbul 34469, Turkey

Abstract

The photoinduced radical generation process has received renewed interest due to its economic and ecological appeal. Herein the light-induced cross-linking of functional polyglycidol and its post-cross-linking modification are presented. Linear polyglycidol was first functionalized with a tertiary amine in a two-step reaction. Dimethylaminopropyl functional polyglycidol was cross-linked in a UV-light mediated reaction with camphorquinone as a type II photoinitiator. The cross-linked polyglycidol was further functionalized by quaternization with various organoiodine compounds. Aqueous dispersions of the cross-linked polymers were investigated by means of DLS and zeta potential measurements. Polymer films were evaluated by DSC and XPS.

Graphical abstract: Light-induced cross-linking and post-cross-linking modification of polyglycidol

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C7CC09498A
Article type
Communication
Submitted
11 Dec 2017
Accepted
22 Jan 2018
First published
26 Jan 2018

Chem. Commun., 2018,54, 1647-1650

Permissions

Request permissions

Light-induced cross-linking and post-cross-linking modification of polyglycidol

F. Marquardt, M. Bruns, H. Keul, Y. Yagci and M. Möller, Chem. Commun., 2018, 54, 1647 DOI: 10.1039/C7CC09498A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements