Issue 66, 2019
From the journal:

Chemical Communications

Kolbe–Schmitt type reaction under ambient conditions mediated by an organic base†

Yuta Sadamitsu,a   Akira Okumura,a   Kodai Saitoa  and  Tohru Yamada ORCID logo *a  

* Corresponding authors

a Department of Chemistry, Keio University, Hiyoshi, Kohoku-ku, Yokohama 223-8522, Japan
E-mail: yamada@chem.keio.ac.jp

Abstract

The combined use of an organic base for resorcinols realized a Kolbe–Schmitt type reaction under ambient conditions. When resorcinols (3-hydroxyphenol derivatives) were treated with DBU under a carbon dioxide atmosphere, nucleophilic addition to carbon dioxide proceeded to afford the corresponding salicylic acid derivatives in high yields.

Graphical abstract: Kolbe–Schmitt type reaction under ambient conditions mediated by an organic base

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Article information

DOI
https://doi.org/10.1039/C9CC04550C
Article type
Communication
Submitted
13 Jun 2019
Accepted
19 Jul 2019
First published
31 Jul 2019

Chem. Commun., 2019,55, 9837-9840

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Kolbe–Schmitt type reaction under ambient conditions mediated by an organic base

Y. Sadamitsu, A. Okumura, K. Saito and T. Yamada, Chem. Commun., 2019, 55, 9837 DOI: 10.1039/C9CC04550C

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