Tolerant to air σ-alkane complexes by surface modification of single crystalline solid-state molecular organometallics using vapour-phase cationic polymerisation: SMOM@polymer

Alexander J. Bukvic; Dana Georgiana Crivoi; Hollie G. Garwood; Alasdair I. McKay; Thomas T. D. Chen; Antonio J. Martínez-Martínez; Andrew S. Weller

doi:10.1039/D0CC01140A

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Tolerant to air σ-alkane complexes by surface modification of single crystalline solid-state molecular organometallics using vapour-phase cationic polymerisation: SMOM@polymer†

Alexander J. Bukvic,

^ab Dana Georgiana Crivoi,^b Hollie G. Garwood,^b Alasdair I. McKay,

^b Thomas T. D. Chen,^b Antonio J. Martínez-Martínez

^b and Andrew S. Weller

*^a

Author affiliations

* Corresponding authors

^a Department of Chemistry, University of York, Heslington, York, UK

^b Department of Chemistry, University of Oxford, Oxford, UK
E-mail: andrew.weller@york.ac.uk

Abstract

Vapour-phase surface-initiated cationic polymerisation of ethylvinylether occurs at single-crystals of the σ-alkane complex [Rh(Cy₂PCH₂CH₂PCy₂)(NBA)][BAr^F₄]. This new surface interface makes these normally very air sensitive materials tolerant to air, while also allowing for onward single-crystal to single-crystal reactivity at metal sites within the lattice.

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DOI: https://doi.org/10.1039/D0CC01140A
Article type: Communication
Submitted: 12 Feb 2020
Accepted: 05 Mar 2020
First published: 19 Mar 2020
This article is Open Access

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Chem. Commun., 2020,56, 4328-4331

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Tolerant to air σ-alkane complexes by surface modification of single crystalline solid-state molecular organometallics using vapour-phase cationic polymerisation: SMOM@polymer

A. J. Bukvic, D. G. Crivoi, H. G. Garwood, A. I. McKay, T. T. D. Chen, A. J. Martínez-Martínez and A. S. Weller, Chem. Commun., 2020, 56, 4328 DOI: 10.1039/D0CC01140A

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Chemical Communications

Tolerant to air σ-alkane complexes by surface modification of single crystalline solid-state molecular organometallics using vapour-phase cationic polymerisation: SMOM@polymer†

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Tolerant to air σ-alkane complexes by surface modification of single crystalline solid-state molecular organometallics using vapour-phase cationic polymerisation: SMOM@polymer

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