Mixed donor, phenanthroline photoactive MOFs with favourable CO2 selectivity

Caitlin J. Setter; Michael B. Price; Luke Conte; Wolfgang Schmitt; Stuart R. Batten; Christopher Richardson; Matthew R. Hill; Ravichandar Babarao; Lauren K. Macreadie

doi:10.1039/D0CC05715K

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Mixed donor, phenanthroline photoactive MOFs with favourable CO₂ selectivity†

Caitlin J. Setter,^ab Michael B. Price,^c Luke Conte,^d Wolfgang Schmitt,

^e Stuart R. Batten,

^f Christopher Richardson,

^d Matthew R. Hill,

^bg Ravichandar Babarao

^h and Lauren K. Macreadie

*^agi

Author affiliations

* Corresponding authors

^a School of Fundamental Sciences, Massey University, Palmerston North, New Zealand

^b Department of Chemical Engineering, Monash University, Clayton, Victoria 3800, Australia

^c School of Chemical and Physical Sciences, Victoria University of Wellington, Wellington 6140, New Zealand

^d School of Chemistry and Molecular Bioscience, University of Wollongong, Wollongong, NSW 2522, Australia

^e School of Chemistry & SFI AMBER Centre, Trinity College Dublin, Dublin 2, Ireland

^f School of Chemistry, Monash University, Clayton, Victoria 3800, Australia

^g CSIRO, Normanby Road, Clayton, Victoria 3168, Australia

^h School of Science, RMIT University, Melbourne, Victoria 3001, Australia

ⁱ School of Chemistry, University of Sydney, Sydney, NSW 2006, Australia
E-mail: lauren.macreadie@sydney.edu.au

Abstract

Mixed donor phenanthroline-carboxylate linkers were combined with Mn^II or Zn^II to form photoactive MOFs with large pore apertures. The MOFs display high CO₂ adsorption capacities, which consequently causes structural framework flexibility, and align with favorable metrics for selective CO₂ capture. The photophysical properties of the MOFs were investigated, with the Mn^II MOF giving rise to short triplet LMCT lifetimes.

This article is part of the themed collection: Functional Coordination Networks

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Article information

DOI: https://doi.org/10.1039/D0CC05715K
Article type: Communication
Submitted: 23 Aug 2020
Accepted: 02 Sep 2020
First published: 02 Sep 2020

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Chem. Commun., 2020,56, 13377-13380

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Mixed donor, phenanthroline photoactive MOFs with favourable CO₂ selectivity

C. J. Setter, M. B. Price, L. Conte, W. Schmitt, S. R. Batten, C. Richardson, M. R. Hill, R. Babarao and L. K. Macreadie, Chem. Commun., 2020, 56, 13377 DOI: 10.1039/D0CC05715K

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