Issue 3, 2021
From the journal:

Organic Chemistry Frontiers

A cooperative zinc/catalytic indium system for the stereoselective sequential synthesis of (E)-1,3-dienes from carbonyl compounds†

Jorge González-Rodríguez,a   Raquel G. Soengas ORCID logo *a  and  Humberto Rodríguez-Solla ORCID logo *a  

* Corresponding authors

a Departamento de Química Orgánica e Inorgánica, Universidad de Oviedo, Julián Clavería 7, Oviedo, Spain
E-mail: rsoengas@uniovi.es, hrsolla@uniovi.es

Abstract

Herein we describe a cooperative zinc/indium system for the stereoselective synthesis of highly functionalized (E)-1,3-dienes through the sequential allylation/elimination reaction of aldehydes and ketones with 1,3-dichloropropene. The main advantages of this methodology are that it has a broad substrate scope and simple procedure, requires mild conditions and is easy to operate.

Graphical abstract: A cooperative zinc/catalytic indium system for the stereoselective sequential synthesis of (E)-1,3-dienes from carbonyl compounds

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/D0QO01388A
Article type
Research Article
Submitted
09 Nov 2020
Accepted
30 Nov 2020
First published
08 Dec 2020

Org. Chem. Front., 2021,8, 591-598

Permissions

Request permissions

A cooperative zinc/catalytic indium system for the stereoselective sequential synthesis of (E)-1,3-dienes from carbonyl compounds

J. González-Rodríguez, R. G. Soengas and H. Rodríguez-Solla, Org. Chem. Front., 2021, 8, 591 DOI: 10.1039/D0QO01388A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements