Issue 10, 2021
From the journal:

Journal of Materials Chemistry A

[Fe(bpy)3]2+-based porous organic polymers with boosted photocatalytic activity for recyclable organic transformations†

Hong-Kun Liu,a   Yi-Fei Lei,a   Peng-Ju Tian,b   Hui Wang,a   Xin Zhao,b   Zhan-Ting Li ORCID logo *a  and  Dan-Wei Zhang ORCID logo *a  

* Corresponding authors

a Department of Chemistry, Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Fudan University, 2205 Songhu Lu, Shanghai 200438, China
E-mail: ztli@fudan.edu.cn, zhangdw@fudan.edu.cn

b Key Laboratory of Synthetic and Self-Assembly Chemistry for Organic Functional Molecules, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Lu, China

Abstract

Three rigid metal porous organic polymers (POPs) based on an iron(II) complex are prepared from the condensation reactions of an octahedral [Fe(bpy)3]2+-cored hexaaldehyde and three rod-like aromatic diamines. The POPs have been studied as the first series of earth-abundant metal complex-connected photocatalysts for heterogeneous visible light-driven oxidation of benzyl halides and enantioselective α-alkylation of aldehydes. Both yields and enantioselectivities of the reactions catalyzed by one of the POPs, which possesses the largest porosity, rival or even surpass those of the reactions homogeneously catalyzed by control [Fe(bpy)3]2+ complexes. Moreover, POP catalysts are highly stable and exhibit a considerable activity after recycling 10 times.

Graphical abstract: [Fe(bpy)3]2+-based porous organic polymers with boosted photocatalytic activity for recyclable organic transformations

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Article information

DOI
https://doi.org/10.1039/D0TA12267J
Article type
Paper
Submitted
18 Dec 2020
Accepted
01 Feb 2021
First published
01 Feb 2021

J. Mater. Chem. A, 2021,9, 6361-6367

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[Fe(bpy)3]2+-based porous organic polymers with boosted photocatalytic activity for recyclable organic transformations

H. Liu, Y. Lei, P. Tian, H. Wang, X. Zhao, Z. Li and D. Zhang, J. Mater. Chem. A, 2021, 9, 6361 DOI: 10.1039/D0TA12267J

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