Issue 4, 2022
From the journal:

Chemical Communications

Chirality inversion in hydrogen-bonded rhodanine–oligothiophene derivatives by solvent and temperature†

Ana M. Garcia ORCID logo a  and  Amparo Ruiz-Carretero ORCID logo *a  

* Corresponding authors

a University of Strasbourg, CNRS, Institut Charles Sadron, 23 Rue de Loess, BP 84047, Strasbourg 67034, Cedex 2, France
E-mail: amparo.ruiz@ics-cnrs.unistra.fr

Abstract

The self-assembly process of hydrogen-bonded quinquethiophene–rhodanine derivatives has been explored as a function of solvent and temperature. We demonstrate the divergent supramolecular chirality emerging from a single enantiomer by subtle changes in solvent mixtures and sample preparation protocol. Spectroscopic techniques have proved the presence of aggregates where H-bonding interactions play a crucial role.

Graphical abstract: Chirality inversion in hydrogen-bonded rhodanine–oligothiophene derivatives by solvent and temperature

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Article information

DOI
https://doi.org/10.1039/D1CC05945A
Article type
Communication
Submitted
21 Oct 2021
Accepted
07 Dec 2021
First published
08 Dec 2021

Chem. Commun., 2022,58, 529-532

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Chirality inversion in hydrogen-bonded rhodanine–oligothiophene derivatives by solvent and temperature

A. M. Garcia and A. Ruiz-Carretero, Chem. Commun., 2022, 58, 529 DOI: 10.1039/D1CC05945A

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