Issue 20, 2021

Broadening the scope of high structural dimensionality nanomaterials using pyridine-based curcuminoids

Abstract

We present a new heteroditopic ligand (3pyCCMoid) that contains the typical skeleton of a curcuminoid (CCMoid) decorated with two 3-pyridyl groups. The coordination of 3pyCCMoid with ZnII centres results in a set of novel coordination polymers (CPs) that display different architectures and dimensionalities (from 1D to 3D). Our work analyses how synthetic methods and slight changes in the reaction conditions affect the formation of the final materials. Great efforts have been devoted toward understanding the coordination entities that provide high dimensional systems, with emphasis on the characterization of 2D materials, including analyses of different types of substrates, stability and exfoliation in water. Here, we foresee the great use of CCMoids in the field of CPs and emphasize 3pyCCMoid as a new-born linker.

Graphical abstract: Broadening the scope of high structural dimensionality nanomaterials using pyridine-based curcuminoids

Supplementary files

Article information

Article type
Paper
Submitted
02 Mar 2021
Accepted
14 Apr 2021
First published
29 Apr 2021
This article is Open Access
Creative Commons BY-NC license

Dalton Trans., 2021,50, 7056-7064

Broadening the scope of high structural dimensionality nanomaterials using pyridine-based curcuminoids

L. Rodríguez-Cid, W. Qian, J. Iribarra-Araya, Á. Etcheverry-Berríos, E. Martínez-Olmos, D. Choquesillo-Lazarte, E. C. Sañudo, O. Roubeau, A. M. López-Periago, A. González-Campo, J. G. Planas, M. Soler, C. Domingo and N. Aliaga-Alcalde, Dalton Trans., 2021, 50, 7056 DOI: 10.1039/D1DT00708D

This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. You can use material from this article in other publications, without requesting further permission from the RSC, provided that the correct acknowledgement is given and it is not used for commercial purposes.

To request permission to reproduce material from this article in a commercial publication, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party commercial publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements