Metal carbonyl complexes are almost exclusively found in a low-spin state due to the strong-field nature of the CO ligand. Here the characterisation of highly labile three-coordinate metal(I) monocarbonyl complexes of iron and cobalt is presented. Experimental and quantum chemical examinations reveal their high-spin configuration.
C. Schneider, L. Guggolz and C. G. Werncke, Dalton Trans., 2022, 51, 179 DOI: 10.1039/D1DT03924E
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