Issue 10, 2022
From the journal:

New Journal of Chemistry

Silver(i)-catalyzed oxidative coupling of hydrosilanes with DMF to symmetrical and unsymmetrical disiloxanes†

Nan Wu,‡a   Chuang Li,‡a   Guichao Dong,‡a   Mengfei Jianga  and  Zhou Xu ORCID logo *a  

* Corresponding authors

a Key Laboratory of New Drug Research and Clinical Pharmacy, School of Pharmacy, Xuzhou Medical University, Tongshan Road 209, Xuzhou, China
E-mail: xuzhou@xzhmu.edu.cn

Abstract

A range of unsymmetrical and symmetrical disiloxanes have been effectively synthesized through oxidative coupling of hydrosilanes with DMF as a source of oxygen catalyzed by 0.5% AgNTf2 at 60 °C. This protocol features good functional group compatibility, high efficiency and mild reaction conditions. Notably, the reaction could proceed at gram scales with slightly longer reaction times with no decrease in yield.

Graphical abstract: Silver(i)-catalyzed oxidative coupling of hydrosilanes with DMF to symmetrical and unsymmetrical disiloxanes

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Article information

DOI
https://doi.org/10.1039/D1NJ05617D
Article type
Paper
Submitted
24 Nov 2021
Accepted
09 Feb 2022
First published
09 Feb 2022

New J. Chem., 2022,46, 4814-4818

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Silver(I)-catalyzed oxidative coupling of hydrosilanes with DMF to symmetrical and unsymmetrical disiloxanes

N. Wu, C. Li, G. Dong, M. Jiang and Z. Xu, New J. Chem., 2022, 46, 4814 DOI: 10.1039/D1NJ05617D

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