Issue 12, 2023

Towards frustration in Eu(ii) Archimedean tessellations

Abstract

Self-assembly of trans-{EuI2} nodes and ditopic ligands leads to isoreticular 2D frameworks featuring a rare, non-kagome Archimedean tessellation. The topology and intra-layer Eu(II)–Eu(II) antiferromagnetic interactions provide the prerequisites for geometrical spin frustration, which, due to the spin state degeneracy, is key for novel phenomena such as enhanced magnetic refrigeration.

Graphical abstract: Towards frustration in Eu(ii) Archimedean tessellations

Supplementary files

Article information

Article type
Communication
Submitted
17 Nov 2022
Accepted
14 Dec 2022
First published
14 Dec 2022

Chem. Commun., 2023,59, 1609-1612

Towards frustration in Eu(II) Archimedean tessellations

H. Chen, A. S. Manvell, M. Kubus, M. A. Dunstan, G. Lorusso, D. Gracia, M. S. B. Jørgensen, S. Kegnæs, F. Wilhelm, A. Rogalev, M. Evangelisti and K. S. Pedersen, Chem. Commun., 2023, 59, 1609 DOI: 10.1039/D2CC06224K

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