Issue 0, 1976

Conformational properties of a polymer confined between two adsorbing surfaces

Abstract

We have studied the conformation of an ideal polymer confined between two planar adsorbing surfaces. “Confined” means that one segment is permanently adsorbed to one of the surfaces. “Ideal” means that the distance between segments is governed by an angle-independent (freely rotating) probability density function with characteristic length a. The segment/surface interaction is determined by an adsorption parameter W. Segment/segment interactions are neglected. We show that for identical surfaces separated by a distance l, (i) if W/a < 1, the pressure is positive and the average segment density distribution has a maximum midway between the plates, (ii) if W/a > 1, the pressure is negative and most of the beads are strongly adsorbed.

No turning points were found for the pressure regardless of the value of W/a. A summary of the results for the pressure, fraction of segments adsorbed and the density of segments between the plates for different values of the adsorption strength, W/a, is tabulated. For different surfaces, one with adsorption parameter W0, the other with zero adsorption parameter, the pressure is always positive regardless of the value of W0.

Article information

Article type
Paper

J. Chem. Soc., Faraday Trans. 2, 1976,72, 1584-1602

Conformational properties of a polymer confined between two adsorbing surfaces

D. Chan, B. Davies and P. Richmond, J. Chem. Soc., Faraday Trans. 2, 1976, 72, 1584 DOI: 10.1039/F29767201584

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements