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Synlett 1998; 1998(1): 35-36
DOI: 10.1055/s-1998-1583
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Chemical Manganese Dioxide (CMD), an Efficient Activated Manganese Dioxide. Application to Oxidation of Benzylic and Allylic Alcohols

Toyohiko Aoyama* , Naoko Sonoda, Mariko Yamauchi, Kyoko Toriyama, Masahiro Anzai, Akira Ando, Takayuki Shioiri
  • *Faculty of Pharmaceutical Sciences, Nagoya City University, Tanabe-dori, Mizuho-ku, Nagoya 467, Japan; Fax +81-52-8 34-41 72; E-mail: shioiri@phar.nagoya-cu.ac.jp
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Publication History

Publication Date:
31 December 2000 (online)

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Oxidation of benzylic and allylic alcohols with chemical manganese dioxide smoothly proceeded under mild reaction conditions to give the corresponding aldehydes and ketones, respectively, in high yields.

chemical manganese dioxide - CMD - benzylic alcohol - allylic alcohol - oxidation

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