Resonance interaction and self-broadening of alkali resonance lines. I. Adiabatic potential curves

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, , Citation M Movre and G Pichler 1977 J. Phys. B: Atom. Mol. Phys. 10 2631 DOI 10.1088/0022-3700/10/13/016

0022-3700/10/13/2631

Abstract

Adiabatic potential curves were calculated using perturbation theory for the long-range electrostatic interaction between two alkali atoms of the same species, one being in the ground state, the other in the resonance-excited state. Comparison with recent experiments showed that the observed satellites and asymmetries in the self-broadened quasi-state wings of the alkali resonance lines are the consequence of extrema in certain potential curves between the fine-structure levels.

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10.1088/0022-3700/10/13/016