Theory of collision-induced absorption for spherical top molecules

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, , Citation C G Gray 1971 J. Phys. B: Atom. Mol. Phys. 4 1661 DOI 10.1088/0022-3700/4/12/014

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1 CNRS, Bellevue, France

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0022-3700/4/12/1661

Abstract

The quantum theory of the integrated absorption coefficient for the collision-induced far infrared rotation-translation spectrum of spherical top molecules is developed. The most general multipolar induction mechanism is considered. A spectral moment is also discussed. Applications are given for the molecules CH4, CD4, CF4 and SF6.

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