Extended Analysis of Mo VI

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, , Citation B Edlén et al 1985 Phys. Scr. 32 215 DOI 10.1088/0031-8949/32/3/008

1402-4896/32/3/215

Abstract

The analysis of the RbI-like spectrum Mo VI has been extended to include a total of some 110 classified lines and 44 energy levels belonging to the one-electron configurations 4s24p6(1S) nl with n ranging up to 9 and l up to 7. The analysis is based on recordings of vacuum spark spectra made at Lund in the region 230-2350 Å, complemented by a list of lines from 2193 to 6336 Å observed and identified by Romanov and Striganov in a Penning type arc discharge. The one-electron level system is partly mixed with core-excited configurations, not treated in the present paper. Especially the nf series is strongly perturbed by 4s24p54d2, and an anomalous behaviour of the ng series is explained by interaction with the 2G term of 4s4p64d2. The ionization limit, derived from 6h, 7i and 8k by means of the polarization formula, is found to be 555 132 ± 2 cm-1.

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10.1088/0031-8949/32/3/008