Relaxations in molecularly thin liquid films

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Published under licence by IOP Publishing Ltd
, , Citation A Levent Demirel and Steve Granick 1996 J. Phys.: Condens. Matter 8 9537 DOI 10.1088/0953-8984/8/47/058

0953-8984/8/47/9537

Abstract

The linear viscoelastic behaviour of molecularly thin OMCTS (octamethylcyclotetrasiloxane) films has been studied as a function of film thickness using a modified surface forces apparatus. The frequency spectra of viscoelastic relaxation measured at different film thicknesses superposed onto a master curve when each spectrum was shifted horizontally and vertically with respect to the frequency spectrum at a reference film thickness. The master curve indicates a wide separation between two sets of viscoelastic relaxations and suggests a gradual glass-like transition to solidity.

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10.1088/0953-8984/8/47/058