Isothermal and high-pressure studies of dielectric relaxation in supercooled glycerol

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Published under licence by IOP Publishing Ltd
, , Citation M Paluch et al 1996 J. Phys.: Condens. Matter 8 10885 DOI 10.1088/0953-8984/8/50/014

0953-8984/8/50/10885

Abstract

Measurements of isothermal (), high-pressure behaviour (up to 270 MPa) of complex electric permittivity in supercooled glycerol are presented. The observed peaks of relaxation in absorption curves show increasing relaxation time with increasing pressure. The behaviour of can be reproduced by the pressure version of an Arrhenius relation or by a modified Vogel - Fulcher - Tammann equation. The data obtained can be superimposed by applying the scaling form used by Dixon et al 1990 Phys. Rev. Lett. 65 1108.

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10.1088/0953-8984/8/50/014