Abstract
This paper describes an experimental and theoretical examination of a 10-μg -axis-oriented single crystal of MnAs. The critical magnetic field for the first-order transition to the ferromagnetic phase has been measured as a function of temperature (15 to 65°C) and pressure (0 to 1000 bars gauge), using miniature-coil pulsed fields to 110 kOe. Data analysis substantiates the thesis of the recent Bean-Rodbell theory on magnetic first-order phase transitions that the transition in MnAs near 45°C is between ferromagnetic and paramagnetic phases and arises from a sufficiently sensitive dependence of exchange energy on lattice strain and a sufficiently high compressibility. The match between theory and experiment yields a compressibility of 4.55× , a lattice thermal expansion coefficient of 5.71×/°C, an apparent paramagnetic Curie temperature of 277.1°K, and a Curie-temperature dependence on volume strain, , of 18.9, where is the Curie temperature of the unstrained specimen at 0°K. Discrepancies in the match suggest a primary need to include short-range order in the theory. Auxiliary experiments show the magnetocrystalline anisotropy sum, , to be about -7.6 and -12.0× ergs/ at 299 and 77°K, respectively.
- Received 8 January 1963
DOI:https://doi.org/10.1103/PhysRev.130.1347
©1963 American Physical Society