Color Centers Produced in KCl and KBr by Prolonged X Irradiations at Low Temperatures

Bruce J. Faraday and W. Dale Compton
Phys. Rev. 138, A893 – Published 3 May 1965
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Abstract

The principal purposes of this study were to observe the effect of an x irradiation of extended duration on the production of color centers in KCl and KBr at low temperatures and to examine the implications with regard to possible color-center models. Growth curves were determined at 5°K for the F, K, M, and H bands in KCl and KBr and for a new band at 245 mμ in KCl and at 278 mμ in KBr, called the H band. Growth curves were determined at 80°K for the F, K, and M bands in KCl and KBr. The growth of the V4 band in KBr and of a band having its absorption maximum at 240 mμ in KCl, designated as the V(240) band, was also followed at 80°K. The ratio of the absorptions at the peak of the F and K bands was found to remain constant indicating that both of these bands arise from transitions in the same center. The concentration of M centers was found to depend quadratically on the F-center concentration. This result gives conclusive support to the model proposed by van Doorn and Haven that the M center consists of a pair of associated F centers. The FtoH ratio was observed to be constant for short x-ray exposures, supporting the viewpoint that the two centers are produced as complementary defects; however, for prolonged exposures, this ratio is no longer constant. The number of F centers is in constant ratio to the combined concentrations of H and H centers provided that the oscillator strength of the H band is suitably chosen. The linear dependence of the generation of both V4 centers in KBr and V(240) centers in KCl on F-center concentration suggests that the V4 and V(240) centers, rather than V1 centers, are fundamentally related to the mechanism of formation of F centers near liquid-nitrogen temperature for a prolonged irradiation.

  • Received 5 November 1964

DOI:https://doi.org/10.1103/PhysRev.138.A893

©1965 American Physical Society

Authors & Affiliations

Bruce J. Faraday* and W. Dale Compton

  • U. S. Naval Research Laboratory, Washington, D. C.

  • *A portion of this work was submitted to the faculty of the Catholic University of America in partial fulfillment of the requirements for the degree of Doctor of Philosophy.
  • Present address: Department of Physics, University of Illinois, Urbana, Illinois.

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Vol. 138, Iss. 3A — May 1965

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