Abstract
The paramagnetic resonance of the state of has been studied in the monoclinic symmetry which arises from associated with a monovalent metal impurity (, , or ) in ZnS, ZnSe, ZnTe, CdTe, and ZnO. The and impurities are substitutional for the metal ions at one of the nearest possible sites. The zero-field splitting due to the crystalline electric fields is frequently large compared to the Zeeman interaction. It is observed that no specific ratio of the two quadratic fine-structure terms in the spin Hamiltonian occurs. This suggests that in many cases the observation of nearly isotropic lines near results from a fortuitous set of values for these fine-structure terms, supporting the view that a pure "rhombic" term need not follow from the symmetry of the environment.
- Received 13 December 1967
DOI:https://doi.org/10.1103/PhysRev.169.359
©1968 American Physical Society