Induced Infrared Absorption due to Bound Charge in the Silver Halides

Richard C. Brandt and Frederick C. Brown
Phys. Rev. 181, 1241 – Published 15 May 1969
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Abstract

Induced infrared absorption due to polarons generated by band-to-band light has been studied in AgBr and AgCl at low temperatures. Strong narrow zero-phonon lines with sideband structure are observed. The positions of the sharp far-infrared absorption lines indicate that exciton or bound polaron states of large radius are involved. The results are compared with a nonadiabatic theory for bound polarons. An unusual and extremely slow logarithmic decay of the induced absorption is observed, together with a logarithmic dependence of the induced absorption on the generating intensity. A model consisting of separated electron and hole polaron pairs, as well as alternative models, is discussed.

  • Received 30 December 1968

DOI:https://doi.org/10.1103/PhysRev.181.1241

©1969 American Physical Society

Authors & Affiliations

Richard C. Brandt*,† and Frederick C. Brown

  • Department of Physics and Materials Research Laboratory, University of Illinois, Urbana, Illinois

  • *Work performed in partial fullfillment of the requirements for the Ph.D. degree at the University of Illinois. A preliminary report is to be found in Bull. Am. Phys. Soc.12, 316 (1967) and also inLocalized Excitations in Solids, edited by R. F. Wallis (Plenum Press, Inc., New York, 1968).
  • Present address: Massachusetts Institute Technology Lincoln Laboratory, Lexington, Mass.

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Issue

Vol. 181, Iss. 3 — May 1969

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