Vapor Pressure of Caesium by the Positive Ion Method

John Bradshaw Taylor and Irving Langmuir
Phys. Rev. 51, 753 – Published 1 May 1937
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Abstract

The positive ion currents from pure tungsten filaments in saturated caesium vapor at bulb temperatures from -35°C to +73°C were measured for filament temperatures from 1000° to 1800°K. The results were corrected for the cooling effect of the leads and for photoelectric emission from the caesium film on the platinum deposited on the bulb which was used as an ion collector. The vapor pressures in mm of Hg are given for solid Cs (T<302°K) by log10pS=10.54601.00log10T4150T and for liquid Cs (T>302°K) by log10PL=11.05311.35log10T4041T.

The vapor pressures given by these equations are believed to be accurate to within one percent from 220° to 350°K, within 3 percent up to 600° and within about 8 percent at 1000°K.

  • Received 23 February 1937

DOI:https://doi.org/10.1103/PhysRev.51.753

©1937 American Physical Society

Authors & Affiliations

John Bradshaw Taylor* and Irving Langmuir

  • General Electric Company, Schenectady, New York

  • *Dr. Taylor died January 22, 1937.

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Issue

Vol. 51, Iss. 9 — May 1937

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