Molecular Dipole Moments and Stark Effects. III. Dipole Moment Determinations

R. G. Shulman, B. P. Dailey, and C. H. Townes
Phys. Rev. 78, 145 – Published 15 April 1950
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Abstract

Dipole moments of eight molecules were determined by the Stark splittings of the rotational transitions in the microwave region. The molecules and their moments in Debye units are: AsF3, 2.815±0.025; CH3I, 1.647±0.014; CH3Cl, 1.869±0.010; CH3Br, 1.797±0.015; CH3CF3, 2.321±0.034; PF3, 1.025±0.009; N2O, 0.166±0.002; and ClCN, 2.802±0.020. In all cases Stark effects followed very closely theoretical expectations.

  • Received 30 December 1948

DOI:https://doi.org/10.1103/PhysRev.78.145

©1950 American Physical Society

Authors & Affiliations

R. G. Shulman* and B. P. Dailey

  • Chemistry Department, Columbia University, New York, New York

C. H. Townes

  • Physics Department, Columbia University, New York, New York

  • *Present address: Chemistry Dept., Calif. Inst. of Tech., Pasadena, California.

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Issue

Vol. 78, Iss. 2 — April 1950

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