Abstract
It is shown that the unusual observed saturation behavior of the microwave electron spin resonance associated with centers in KCl, NaCl, and KBr crystals can be accounted for if the overall width is ascribed to interaction between the -center electrons and the nuclear magnetic moments of the ions adjacent to the centers. The measured saturation factor gives for centers in KCl a spin-lattice relaxation time of 2.5× sec at room temperature. The observed saturation behavior in which only the absorption saturates is in marked disagreement with the Kramers-Kronig relations. However it is shown, that the Kramers-Kronig relations are not applicable to saturated systems. Expressions which avoid the use of these relations are presented for saturable systems.
- Received 18 May 1953
DOI:https://doi.org/10.1103/PhysRev.91.1071
©1953 American Physical Society