Parametric integral equation for radial distribution functions

David D. Carley
Phys. Rev. A 10, 863 – Published 1 September 1974
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Abstract

An integral equation is proposed whose solutions approximate the radial distribution functions of classical fluids whose single-type particles interact with pairwise radial forces. The equation contains a parameter which is adjustable to improve moderate- and high-density solutions. The equation is applied to the hard-sphere model of a fluid, solutions are obtained for four densities, and the pressure equation of state is expressed in terms of a 2 × 2 Padé approximant. A single value of the parameter yields pressures which are in excellent agreement with "exact" values.

  • Received 26 March 1974

DOI:https://doi.org/10.1103/PhysRevA.10.863

©1974 American Physical Society

Authors & Affiliations

David D. Carley

  • Department of Physics, Western Michigan University, Kalamazoo, Michigan 49001

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Issue

Vol. 10, Iss. 3 — September 1974

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