Unified model of ultracold molecular collisions

James F. E. Croft, John L. Bohn, and Goulven Quéméner
Phys. Rev. A 102, 033306 – Published 8 September 2020

Abstract

A scattering model is developed for ultracold molecular collisions, which allows inelastic processes, chemical reactions, and complex formation to be treated in a unified way. All these scattering processes and various combinations of them are possible in ultracold molecular gases, and as such this model will allow the rigorous parametrization of experimental results. In addition we show how, once extracted, these parameters can be related to the physical properties of the system, shedding light on fundamental aspects of molecular collision dynamics.

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  • Received 1 June 2020
  • Accepted 11 August 2020

DOI:https://doi.org/10.1103/PhysRevA.102.033306

©2020 American Physical Society

Physics Subject Headings (PhySH)

Atomic, Molecular & Optical

Authors & Affiliations

James F. E. Croft

  • The Dodd-Walls Centre for Photonic and Quantum Technologies, Dunedin 9054, New Zealand and Department of Physics, University of Otago, Dunedin 9054, New Zealand

John L. Bohn

  • JILA, NIST, and Department of Physics, University of Colorado, Boulder, Colorado 80309-0440, USA

Goulven Quéméner

  • Université Paris-Saclay, CNRS, Laboratoire Aimé Cotton, 91405 Orsay, France

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Issue

Vol. 102, Iss. 3 — September 2020

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