Transition-state theory for tunneling in dissipative media

Eli Pollak
Phys. Rev. A 33, 4244 – Published 1 June 1986
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Abstract

The recently developed theory for tunneling in dissipative systems is rederived using quantal transition-state theory. As predicted by Caldeira and Leggett, we find an exponential damping of the tunneling rate at 0 K. The exponential rate enhancement at low temperatures as well as the crossover temperature are also obtained with this approach. Moreover, the rate enhancement is given explicitly in terms of energy transfer from the bath to the dissociative mode. The present derivation includes memory effects.

  • Received 18 November 1985

DOI:https://doi.org/10.1103/PhysRevA.33.4244

©1986 American Physical Society

Authors & Affiliations

Eli Pollak

  • Chemical Physics Department, The Weizmann Institute of Science, 76100 Rehov ot, Israel

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Issue

Vol. 33, Iss. 6 — June 1986

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