New thermodynamic variables for a nonequilibrium system

Aaron B. Corbet
Phys. Rev. A 9, 1371 – Published 1 March 1974; Erratum Phys. Rev. A 10, 1010 (1974)
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Abstract

The information-theoretic formulation of statistical mechanics is applied to an ideal gas transporting energy without transporting mass. It is shown that the thermal state variables fracture into distinct populations, thus exhibiting a radical sort of local nonequilibrium. The partition function is found in exact form, for an arbitrarily large temperature gradient. In an approximation, it is shown that these results reduce to the known ones for equilibrium, and near equilibrium. The same approximation allows us specific equations for the temperature, pressure tensor, and the entropy of the system, in a far-from-equilibrium case, in terms of the new thermal variables of the system. The general entropy functional, and its variation, are discussed.

  • Received 26 January 1973

DOI:https://doi.org/10.1103/PhysRevA.9.1371

©1974 American Physical Society

Erratum

Erratum: New thermodynamic variables for a nonequilibrium system

Aaron B. Corbet
Phys. Rev. A 10, 1010 (1974)

Authors & Affiliations

Aaron B. Corbet*

  • Biophysics Research Division, Institute of Science and Technology, University of Michigan, Ann Arbor, Michigan 48105

  • *National Institute of Health predoctoral trainee.

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Vol. 9, Iss. 3 — March 1974

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