We present a study of Seebeck and Nernst effect in combination with magnetoresistance and Hall measurements of the Kagome superconductor ${\mathrm{CsV}}_3{\mathrm{Sb}}_5$. A sizable magneto-Seebeck signal appears once the charge density wave (CDW) order sets in below $T_{\text{CDW}}=94$ K. The Nernst signal peaks at a lower temperature $T^{*}\sim 35\mathrm{K}$, crossing which the Hall coefficient switches sign, which we attribute to the ambipolar transport of compensated bands due to the multiband nature of ${\mathrm{CsV}}_3{\mathrm{Sb}}_5$. Sublinear Nernst signal and Hall resistivity also develop well below the CDW transition, which becomes apparent below $T^{*}$. These findings suggest that, the multiband electronic profile plays an important role in the transport properties of the CDW state in ${\mathrm{CsV}}_3{\mathrm{Sb}}_5$.

• Received 4 October 2021
• Revised 8 November 2021
• Accepted 11 November 2021

DOI:https://doi.org/10.1103/PhysRevB.104.L180508