Abstract
Nominally undoped YAl shows broad intense absorption bands in the visible after irradiation with visible and near uv light at 77 K; they become especially strong after subsequent irradiation with near ir. The bands could be correlated with an ESR spectrum arising from holes, which are trapped at ions near unidentified defects or are possibly self-trapped. A similar spectrum appeared after heating to 200 K. It was rather weak and a corresponding absorption could not definitely be identified. The optical absorption is explained by treating the holes together with their accompanying lattice distortions as small polarons. A theory based on this model is presented which is a generalization of an earlier treatment of bound-small-polaron absorption. Information on further absorption of the crystals up to 4 eV is given. Most of this absorption is related to the formation or quenching of the polaron bands.
- Received 18 November 1974
DOI:https://doi.org/10.1103/PhysRevB.11.4201
©1975 American Physical Society