Abstract
We present the results of magnetic-susceptibility, heat-capacity, electrical-resistivity, and thermoelectric-power measurements on . The crystallographic, magnetic, and electronic transport properties are found to be extremely sensitive to the oxygen-defect concentration . Coupled with x-ray and neutron-diffraction data presented in a companion paper, we find that long-range antiferromagnetic order develops with increasing out of a nonmagnetic ground state at into a state with a maximum Néel temperature of 290 K at .
- Received 20 May 1987
DOI:https://doi.org/10.1103/PhysRevB.36.4007
©1987 American Physical Society