High-frequency dielectric loss of Na β-alumina: Evidence for relaxation crossover

K. L. Ngai and U. Strom
Phys. Rev. B 38, 10350 – Published 15 November 1988
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Abstract

The ionic-conductivity (σ) and electric-modulus (M*) data for melt-grown Na β-alumina in the 102107-Hz frequency range have been previously interpreted with a formalism in which the decay of an observable, such as the time-dependent electric field in the sample, follows the (‘‘fractional-exponential’’) form exp[(-t/τ)1n], where 0<n<1. Ionic-conductivity data for frequencies between 108 and 1011 Hz cannot be interpreted in terms of this formalism, but instead the ionic relaxation at high frequencies is consistent with a simple exponential (i.e., with n=0). These observations are in agreement with the predictions of a relaxation model in which the frequency ωc, which defines the crossover from fractional to simple exponential relaxation, is included as an explicit parameter.

  • Received 28 April 1988

DOI:https://doi.org/10.1103/PhysRevB.38.10350

©1988 American Physical Society

Authors & Affiliations

K. L. Ngai and U. Strom

  • Naval Research Laboratory, Washington, D.C. 20375-5000

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Issue

Vol. 38, Iss. 15 — 15 November 1988

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